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Oral presentation

Oral presentation

Structure of water under high pressure and high temperature

Katayama, Yoshinori; Hattori, Takanori; Fukui, Hiroshi*; Nozawa, Akifumi*; Funakoshi, Kenichi*

no journal, , 

Liquid water shows anomalous properties and these properties are attributed to a network structure formed by hydogen-bonded water molecules. To study the structure of water under high pressure, we have carried out in-situ high-pressure high-temperature X-ray diffraction experiments in SPring-8. In addition to the previous X-ray diffraction measurements using a cubic-type multianvil press installed on BL14B1, measurements up to about 17 GPa were successfully carried out using a Kawai-type double-stage press installed on BL04B1. The stcuture factor, $$S(Q)$$, at ambient pressure has two maxima at 2A$$^{-1}$$ and 3A$$^{-1}$$. With increasing pressure, these maxima merged and formed a sharp peak which is resembles that for a simple liquid. Futher compression shifted the peak to larger-Q direction. The increase of density is attributed to an increase of coordination number up to a few GPa and then it is attributed to a decrease of inter-molecular distance at higher pressures.

Oral presentation

Study on structure-factor determination by an energy-dispersive X-ray diffraction method, 2

Katayama, Yoshinori; Kaneko, Hiroshi; Hattori, Takanori

no journal, , 

Energy-despersive X-ray method is commonly used for X-ray diffraction measurements using a cubic-type multi-anvil-press because low background scattering and short data acquisition time can be achieved. However, diffraction intensity is affected by several energy-dependent factors, such as intensity spectrum of synchrotron radiation, sensitivity spectrum of a detector, absorption spectra of sample and surrounding materials. It is difficult to estimate these factors separately, Tsuji et al., proposed a new empirical method to determine structure factor of liquids and glasses. Furthermore, Funakoshi et al., developed a Monte Carlo simulation code to carry out the procedure. But the result is sometimes unstable. We improved the method and reproduce the structure factor of silica glass stably.

Oral presentation

Pressure-temperature stability of InN

Saito, Hiroyuki; Utsumi, Wataru; Kaneko, Hiroshi; Aoki, Katsutoshi

no journal, , 

no abstracts in English

Oral presentation

Infrared spectroscopy for scandium hydride under high pressure; Pressure dependence of optical property and vibrational frequency

Omura, Ayako; Machida, Akihiko; Watanuki, Tetsu; Aoki, Katsutoshi; Takemura, Kenichi*

no journal, , 

no abstracts in English

Oral presentation

Anomalous X-ray scattering of liquid AgI under pressure

Hattori, Takanori; Tomomasa, Masatoshi*; Higaki, Takuya*; Tsuji, Kazuhiko*

no journal, , 

no abstracts in English

Oral presentation

Suspicious amorphous formation in Zr and Ti and the truth

Hattori, Takanori; Saito, Hiroyuki; Kaneko, Hiroshi; Okajima, Yuka; Aoki, Katsutoshi; Utsumi, Wataru

no journal, , 

no abstracts in English

Oral presentation

Pressure-induced structural change in liquids of tetrahedrally bonded materials

Hattori, Takanori

no journal, , 

no abstracts in English

Oral presentation

Thermodynamic studies on the heavy fermion superconductors under high pressure

Tateiwa, Naoyuki; Haga, Yoshinori; Matsuda, Tatsuma; Yamamoto, Etsuji; Ikeda, Shugo; Onuki, Yoshichika*

no journal, , 

We report our thermodynamic studies on the heavy fermion superconductors under high pressure. In this talk, I would like to present basic experimental methods and recent data on the pressure induced superconductor UIr. UIr is a ferromagnet with the Curie temperature 46 K. From previous high pressure studies by the resistivity and magnetic susceptibility measurements, it was clarified that the transition temperature decreases with increasing pressure that multiple ferromagnetic phases (FM1, 2,3) exists under high pressure. We determine the phase boundaries of the FM1, 2, 3 phases by the ac heat capacity measurements under pressures. We will discuss the unusual features of the physical properties in the high pressure phase of UIr.

Oral presentation

Structural transformation of Cd-Yb quasicrystal at low temperature and high pressure

Watanuki, Tetsu; Machida, Akihiko; Aoki, Katsutoshi; Omura, Ayako*; Sato, Taku*; Tsai, A. P.*

no journal, , 

no abstracts in English

Oral presentation

Pressure induced structural transition of YH$$_{3}$$

Machida, Akihiko; Omura, Ayako*; Watanuki, Tetsu; Aoki, Katsutoshi; Takemura, Kenichi*

no journal, , 

no abstracts in English

Oral presentation

Structural transition of LaH$$_{x}$$ under high pressure

Machida, Akihiko; Omura, Ayako*; Watanuki, Tetsu; Aoki, Katsutoshi; Takemura, Kenichi*

no journal, , 

no abstracts in English

Oral presentation

Development of liquid hydrogen loading system for diamond anvil cells

Machida, Akihiko; Omura, Ayako*; Aoki, Katsutoshi

no journal, , 

no abstracts in English

Oral presentation

Phase transition of base machine oil under high pressure, 1; In the case of dicyclohexyl

Nemoto, Kazuaki*; Hirayama, Tomoko*; Matsuoka, Takashi*; Hattori, Takanori

no journal, , 

no abstracts in English

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